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A Redox‐Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions

We report a simple protocol for the photochemical Giese addition of C(sp(3))‐centered radicals to a variety of electron‐poor olefins. The chemistry does not require external photoredox catalysts. Instead, it harnesses the excited‐state reactivity of 4‐alkyl‐1,4‐dihydropyridines (4‐alkyl‐DHPs) to gen...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: van Leeuwen, Thomas, Buzzetti, Luca, Perego, Luca Alessandro, Melchiorre, Paolo
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2019
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519288/
https://ncbi.nlm.nih.gov/pubmed/30747467
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201814497
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