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Alkali metal complexes of an enantiopure iminophosphonamide ligand with bright delayed fluorescence
The enantiomerically pure ligand P,P-diphenyl-N,N′-bis((R)-1-phenylethyl)phosphinimidic amide (1; (R)-HPEPIA) was synthesized and subsequently deprotonated with alkali metal precursors to yield dimeric complexes [M(2){(R)-PEPIA}(2)] (M = Li (2), Na (3), K (4), Rb (5)). The cesium compound [M{(R)-PEP...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6510313/ https://ncbi.nlm.nih.gov/pubmed/31160950 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00629j |
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