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A cyclopentadienyl functionalized silylene – a flexible ligand for Si- and C-coordination
The synthesis of a 1,2,3,4-tetramethylcyclopentadienyl (Cp(4)) substituted four-membered N-heterocyclic silylene [{PhC(NtBu)(2)}Si(C(5)Me(4)H)] is reported first. Then, selected reactions with transition metal and a calcium precursor are shown. The proton of the Cp(4)-unit is labile. This results in...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
The Royal Society of Chemistry
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162997/ https://ncbi.nlm.nih.gov/pubmed/34094449 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04174b |
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