Efficient Blue Phosphorescence in Gold(I)‐Acetylide Functionalized Coinage Metal Bis(amidinate) Complexes

The synthesis of linear symmetric ethynyl‐ and acetylide‐amidinates of the coinage metals is presented. Starting with the desilylation of the complexes [{Me(3)SiC≡CC(NDipp)(2)}(2)M(2)] (Dipp=2,6‐diisopropylphenyl) (M=Cu, Au) it is demonstrated that this compound class is suitable to serve as a versa...

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Publicat a:Chemistry
Autors principals: Feuerstein, Thomas J., Seifert, Tim P., Jung, André P., Müller, Rouven, Lebedkin, Sergei, Kappes, Manfred M., Roesky, Peter W.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756867/
https://ncbi.nlm.nih.gov/pubmed/32520425
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002466
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