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Efficient Blue Phosphorescence in Gold(I)‐Acetylide Functionalized Coinage Metal Bis(amidinate) Complexes

The synthesis of linear symmetric ethynyl‐ and acetylide‐amidinates of the coinage metals is presented. Starting with the desilylation of the complexes [{Me(3)SiC≡CC(NDipp)(2)}(2)M(2)] (Dipp=2,6‐diisopropylphenyl) (M=Cu, Au) it is demonstrated that this compound class is suitable to serve as a versa...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Feuerstein, Thomas J., Seifert, Tim P., Jung, André P., Müller, Rouven, Lebedkin, Sergei, Kappes, Manfred M., Roesky, Peter W.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756867/
https://ncbi.nlm.nih.gov/pubmed/32520425
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002466
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