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Biochemical Approaches for Understanding Iron-sulfur Cluster Regeneration in Escherichia coli Lipoyl Synthase during Catalysis

Lipoyl synthase (LipA in bacteria) is a radical S-adenosylmethionine (SAM) enzyme that catalyzes the second step of the de novo biosynthesis of the lipoyl cofactor: the insertion of sulfur at C6 and C8 of a pendant octanoyl chain. In addition to the [4Fe–4S] cluster that is characteristic of the rad...

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Detalhes bibliográficos
Publicado no:Methods Enzymol
Main Authors: McCarthy, Erin L., Booker, Squire J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6501195/
https://ncbi.nlm.nih.gov/pubmed/30097094
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/bs.mie.2018.06.006
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