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Destruction and Reformation of an Iron-Sulfur Cluster during Catalysis by Lipoyl Synthase

Lipoyl synthase (LipA) catalyzes the last step in the biosynthesis of the lipoyl cofactor, which is the attachment of two sulfhydryl groups to C6 and C8 of a pendant octanoyl chain. The appended sulfur atoms derive from an auxiliary [4Fe–4S] cluster on the protein that is degraded during turnover, l...

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Detalhes bibliográficos
Publicado no:Science
Main Authors: McCarthy, Erin L., Booker, Squire J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5941298/
https://ncbi.nlm.nih.gov/pubmed/29051382
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aan4574
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