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Cobalt Catalyzed Reductive Dimethylcyclopropanation of 1,3-Dienes
Dimethylcyclopropanes are valuable synthetic targets that are challenging to access in high yield using Zn carbenoid reagents. Here, we describe a cobalt-catalyzed variant of the Simmons–Smith reaction that enables the efficient dimethylcyclopropanation of 1,3-dienes using a Me(2)CCl(2)/Zn reagent m...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6489504/ https://ncbi.nlm.nih.gov/pubmed/30144253 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807542 |
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