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Electron Transfer Control of Reductase versus Monooxygenase: Catalytic C–H Bond Hydroxylation and Alkene Epoxidation by Molecular Oxygen

[Image: see text] Catalytic oxidation of organic substrates, using a green oxidant like O(2), has been a long-term goal of the scientific community. In nature, these oxidations are performed by metalloenzymes that generate highly oxidizing species from O(2), which, in turn, can oxidize very stable o...

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Vydáno v:ACS Cent Sci
Hlavní autoři: Mukherjee, Manjistha, Dey, Abhishek
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2019
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6487540/
https://ncbi.nlm.nih.gov/pubmed/31041387
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.9b00046
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