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Synthesis of saccharocin from apramycin and evaluation of its ribosomal selectivity

We describe a straightforward synthesis of the apramycin biosynthetic precursor saccharocin from apramycin by regioselective partial azidation followed by stereoretentive oxidative deamination. Saccharocin was found to exhibit excellent selectivity for inhibition of the bacterial ribosome over the e...

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Detalhes bibliográficos
Publicado no:Medchemcomm
Main Authors: Sarpe, Vikram A., Pirrone, Michael G., Haldimann, Klara, Hobbie, Sven N., Vasella, Andrea, Crich, David
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6482888/
https://ncbi.nlm.nih.gov/pubmed/31057735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9md00093c
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