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Synthesis of saccharocin from apramycin and evaluation of its ribosomal selectivity

We describe a straightforward synthesis of the apramycin biosynthetic precursor saccharocin from apramycin by regioselective partial azidation followed by stereoretentive oxidative deamination. Saccharocin was found to exhibit excellent selectivity for inhibition of the bacterial ribosome over the e...

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Bibliografske podrobnosti
izdano v:Medchemcomm
Main Authors: Sarpe, Vikram A., Pirrone, Michael G., Haldimann, Klara, Hobbie, Sven N., Vasella, Andrea, Crich, David
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2019
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6482888/
https://ncbi.nlm.nih.gov/pubmed/31057735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9md00093c
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