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Racemic Vinylallenes in Catalytic Enantioselective Multicomponent Processes. Rapid Generation of Complexity through 1,6-Conjugate Additions
Racemic vinylallenes are shown to be attractive substrates for catalytic multicomponent diastereo-, and enantioselective 1,6-conjugate addition of multifunctional allyl moieties to easily accessible α,β,γ,δ−unsaturated diesters. Reactions may be catalyzed by 5.0 mol % of a readily accessible NHC–Cu...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6481603/ https://ncbi.nlm.nih.gov/pubmed/30653802 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812535 |
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