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High-Resolution EXAFS Provides Evidence for a Longer Fe•••Fe Distance in the Q Intermediate of Methane Monooxygenase
Despite decades of intense research, the core structure of the methane C-H bond breaking diiron(IV) intermediate, Q, of soluble methane monooxygenase (sMMO) remains controversial, with conflicting reports supporting either a ‘diamond’ diiron core structure or an open-core structure. Early EXAFS data...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6470014/ https://ncbi.nlm.nih.gov/pubmed/30398343 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b10313 |
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