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Branch-Selective Addition of Unactivated Olefins into Imines and Aldehydes

Radical hydrofunctionalization occurs with ease using metal-hydride atom transfer (MHAT) catalysis to couple alkenes and competent radicalophilic electrophiles. Traditional two-electron electrophiles have remained unreactive. Herein we report the reductive coupling of electronically-unbiased olefins...

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Publicat a:J Am Chem Soc
Autors principals: Matos, Jeishla L. M., Vásquez-Céspedes, Suhelen, Gu, Jieyu, Oguma, Takuya, Shenvi, Ryan A.
Format: Artigo
Idioma:Inglês
Publicat: 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6469987/
https://ncbi.nlm.nih.gov/pubmed/30463404
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11699
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