Site‐Selective C−S Bond Formation at C−Br over C−OTf and C−Cl Enabled by an Air‐Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst

This report widens the repertoire of emerging Pd(I) catalysis to carbon–heteroatom, that is, C−S bond formation. While Pd(0)‐catalyzed protocols may suffer from the formation of poisonous sulfide‐bound off‐cycle intermediates and lack of selectivity, the mechanistically diverse Pd(I) catalysis conce...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Scattolin, Thomas, Senol, Erdem, Yin, Guoyin, Guo, Qianqian, Schoenebeck, Franziska
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2018
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6468269/
https://ncbi.nlm.nih.gov/pubmed/30014554
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201806036
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