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Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp(2)) and C(sp(3)) Coupling of C−Br, C−OTf, and C−Cl Bonds Enabled by a Single Palladium(I) Dimer

Full control over multiple competing coupling sites would enable straightforward access to densely functionalized compound libraries. Historically, the site selection in Pd(0)‐catalyzed functionalizations of poly(pseudo)halogenated arenes has been unpredictable, being dependent on the employed catal...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Keaveney, Sinead T., Kundu, Gourab, Schoenebeck, Franziska
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6175235/
https://ncbi.nlm.nih.gov/pubmed/30091504
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808386
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