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Site‐Selective C−S Bond Formation at C−Br over C−OTf and C−Cl Enabled by an Air‐Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst
This report widens the repertoire of emerging Pd(I) catalysis to carbon–heteroatom, that is, C−S bond formation. While Pd(0)‐catalyzed protocols may suffer from the formation of poisonous sulfide‐bound off‐cycle intermediates and lack of selectivity, the mechanistically diverse Pd(I) catalysis conce...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6468269/ https://ncbi.nlm.nih.gov/pubmed/30014554 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201806036 |
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