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Requirements for Lewis Acid Mediated Capture and N-N Bond Cleavage of Hydrazine at Iron

An iron complex bearing a pyridine(dicarbene) pincer was designed to probe the requirements of Lewis acid enabled N(2)H(4) capture and subsequent N-N bond cleavage. Appended boron Lewis acids were installed by two methods to circumvent the incompatibilities associated with Lewis acid/base quenching...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Kiernicki, John J., Zeller, Matthias, Szymczak, Nathaniel K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6467759/
https://ncbi.nlm.nih.gov/pubmed/30628782
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b02433
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