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Arynes and Cyclic Alkynes as Synthetic Building Blocks for Stereodefined Quaternary Centers
We report a facile method to synthesize stereodefined quaternary centers from reactions of arynes and related strained intermediates using β-ketoester-derived substrates. The conversion of β- ketoesters to chiral enamines is followed by reaction with in situ generated strained arynes or cyclic alkyn...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6467087/ https://ncbi.nlm.nih.gov/pubmed/29716194 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b02875 |
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