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Cyclic Alkyne Approach to Heteroatom-Containing Polycyclic Aromatic Hydrocarbon Scaffolds

We report a modular synthetic strategy for accessing heteroatom-containing polycyclic aromatic hydrocarbons (PAHs). Our approach relies on the controlled generation of transient heterocyclic alkynes and arynes. The strained intermediates undergo in situ trapping with readily accessible oxadiazinones...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Darzi, Evan R., Barber, Joyann S., Garg, Neil K.
Format: Artigo
Language:Inglês
Published: 2019
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6663605/
https://ncbi.nlm.nih.gov/pubmed/31087805
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903060
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