Loading...
An efficient synthesis of the guaiane sesquiterpene (−)-isoguaiene by domino metathesis
(−)-Isoguaiene was prepared from (S)-citronellal in only 9–10 steps with good overall yields. Either a trienyne or a dienediyne metathesis and highly diastereoselective organocatalytic Michael additions of aldehydes derived from (S)-citronellal served as the key transformations.
Na minha lista:
| Udgivet i: | Beilstein J Org Chem |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2019
|
| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6466796/ https://ncbi.nlm.nih.gov/pubmed/31019578 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.83 |
| Tags: |
Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!
|