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An efficient synthesis of the guaiane sesquiterpene (−)-isoguaiene by domino metathesis
(−)-Isoguaiene was prepared from (S)-citronellal in only 9–10 steps with good overall yields. Either a trienyne or a dienediyne metathesis and highly diastereoselective organocatalytic Michael additions of aldehydes derived from (S)-citronellal served as the key transformations.
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| Publicado en: | Beilstein J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Beilstein-Institut
2019
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6466796/ https://ncbi.nlm.nih.gov/pubmed/31019578 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.83 |
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