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Substrate-Controlled Direct α-Stereoselective Synthesis of Deoxyglycosides from Glycals Using B(C(6)F(5))(3) as Catalyst
[Image: see text] B(C(6)F(5))(3) enables the metal-free unprecedented substrate-controlled direct α-stereoselective synthesis of deoxyglycosides from glycals. 2,3-Unsaturated α-O-glycoside products are obtained with deactivated glycals at 75 °C in the presence of the catalyst, while 2-deoxyglycoside...
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| Publicado no: | J Org Chem |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2019
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6466476/ https://ncbi.nlm.nih.gov/pubmed/30706711 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b02613 |
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