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Palladium-Catalyzed α-Stereoselective O-Glycosylation of O(3)-Acylated Glycals

[Image: see text] Pd(MeCN)(2)Cl(2) enables the α-stereoselective catalytic synthesis of 2,3-unsaturated O-glycosides from O(3)-acylated glycals without the requirement for additives to preactivate either donor or nucleophile. Mechanistic studies suggest that, unlike traditional (η3-allyl)palladium-m...

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Dettagli Bibliografici
Pubblicato in:Org Lett
Autori principali: Sau, Abhijit, Galan, M. Carmen
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2017
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5479629/
https://ncbi.nlm.nih.gov/pubmed/28514163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01092
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