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Palladium-Catalyzed α-Stereoselective O-Glycosylation of O(3)-Acylated Glycals
[Image: see text] Pd(MeCN)(2)Cl(2) enables the α-stereoselective catalytic synthesis of 2,3-unsaturated O-glycosides from O(3)-acylated glycals without the requirement for additives to preactivate either donor or nucleophile. Mechanistic studies suggest that, unlike traditional (η3-allyl)palladium-m...
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2017
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5479629/ https://ncbi.nlm.nih.gov/pubmed/28514163 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b01092 |
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