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A Semi-Synthesis of an Anticancer DPAGT1 Inhibitor from a Muraymycin Biosynthetic Intermediate

We have explored a method to convert a muraymycin biosynthetic intermediate 3 to an anticancer drug lead 2 for in vivo and thorough preclinical studies. Cu(OAc)(2) forms a stable complex with the amide 4 and it prevents electrophilic reactions at the 2-((3-aminopropyl)amino)acetamide moiety. Under t...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Mitachi, Katsuhiko, Kurosu, Shou M., Eslamimehr, Shakiba, Lemieux, Maddie R., Ishizaki, Yoshimasa, Clemons, William M., Kurosu, Michio
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6447083/
https://ncbi.nlm.nih.gov/pubmed/30698984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b03716
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