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Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides
Molecular uranium-nitrides are now well known, but there are no isolable molecular thorium-nitrides outside of cryogenic matrix isolation experiments. We report that treatment of [M(Tren(DMBS))(I)] (M = U, 1; Th, 2; Tren(DMBS) = {N(CH(2)CH(2)NSiMe(2)Bu(t))(3)}(3–)) with NaN(3) or KN(3), respectively...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6446963/ https://ncbi.nlm.nih.gov/pubmed/30996964 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05473h |
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