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Photoredox-catalyzed Site-selective α-C(sp(3))-H Alkylation of Primary Amine Derivatives
The synthetic utility of tertiary amines to oxidatively generate α-amino radicals is well established; however, primary amines remain challenging due to competitive side reactions. This report describes the site-selective α-functionalization of primary amine derivatives through the generation of α-a...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6442930/ https://ncbi.nlm.nih.gov/pubmed/30768740 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201812227 |
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