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Directed γ-C(sp(3))-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis
Visible light photoredox catalysis enables direct γ-C(sp3)-H alkylation of saturated aliphatic carbonyl compounds. Electron-deficient alkenes are used as the coupling partners in this reaction. Distinguished site selectivity is controlled by the predominant 1,5-hydrogen atom transfer (HAT) of an ami...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5851452/ https://ncbi.nlm.nih.gov/pubmed/29022709 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09306 |
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