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A new route for the efficient metalation of unfunctionalized aromatics
The synthesis and isolation of a novel bimetallic species formed by reacting two equivalents of TMPLi with CuCl in the presence of Et(2)O are reported. X-ray crystallography reveals the Et(2)O-free tetranuclear aggregate (TMPCu)(2)(TMPLi)(2)1, which formally results from the catenation of dimers of...
Shranjeno v:
| izdano v: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2019
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6429619/ https://ncbi.nlm.nih.gov/pubmed/30996927 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04325f |
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