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Metal exchange in lithiocuprates: implications for our understanding of structure and reactivity

New reagents have been sought for directed ortho cupration in which the use of cyanide reagents is eliminated. CuOCN reacts with excess TMPLi (TMP = 2,2,6,6-tetramethylpiperidide) in the presence of limited donor solvent to give crystals that are best represented as (TMP)(2)Cu(0.1)Li(0.9)(OCN)Li(2)(...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Peel, Andrew J., Ackroyd, Ryan, Wheatley, Andrew E. H.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5603898/
https://ncbi.nlm.nih.gov/pubmed/28959414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01423f
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