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Metal exchange in lithiocuprates: implications for our understanding of structure and reactivity

New reagents have been sought for directed ortho cupration in which the use of cyanide reagents is eliminated. CuOCN reacts with excess TMPLi (TMP = 2,2,6,6-tetramethylpiperidide) in the presence of limited donor solvent to give crystals that are best represented as (TMP)(2)Cu(0.1)Li(0.9)(OCN)Li(2)(...

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Bibliografski detalji
Izdano u:Chem Sci
Glavni autori: Peel, Andrew J., Ackroyd, Ryan, Wheatley, Andrew E. H.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2017
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5603898/
https://ncbi.nlm.nih.gov/pubmed/28959414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01423f
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