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A new route to N-aromatic heterocycles from the hydrogenation of diesters in the presence of anilines

The hydrogenation of dicarboxylic acids and their esters in the presence of anilines provides a new synthesis of heterocycles. [Ru(acac)(3)] and 1,1,1-tris(diphenylphosphinomethyl)ethane (triphos) gave good to excellent yields of the cyclic amines at 220 °C. When aqueous ammonia was used with dimeth...

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Vydáno v:Chem Sci
Hlavní autoři: Shi, Yiping, Kamer, Paul C. J., Cole-Hamilton, David J., Harvie, Michelle, Baxter, Emma F., Lim, Kate J. C., Pogorzelec, Peter
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2017
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5636942/
https://ncbi.nlm.nih.gov/pubmed/29147516
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01718a
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