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Primary α-tertiary amine synthesis via α-C–H functionalization
A quinone-mediated general synthetic platform for the construction of primary α-tertiary amines from abundant primary α-branched amine starting materials is described. This procedure pivots on the efficient in situ generation of reactive ketimine intermediates and subsequent reaction with carbon-cen...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6429468/ https://ncbi.nlm.nih.gov/pubmed/30996928 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05164j |
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