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Total Synthesis and Biological Activity of the Arachidonic Acid Metabolite Hemiketal E(2)
The total synthesis of hemiketal E(2) (HKE(2)) has been accomplished using a gold(I)-mediated cycloisomerization followed by oxidation of the enol ether product to introduce a unique keto-hemiketal, the core structure of HKE(2). Synthetic hemiketal E(2) reproduced biosynthetically derived HKE(2) in...
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| Publié dans: | Org Lett |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6425725/ https://ncbi.nlm.nih.gov/pubmed/29916257 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b01578 |
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