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Isomerizations of Propargyl 3-Acylpropiolates via Reactive Allenes

Thermal isomerizations of various propargyl 3-acylpropiolates are described. Many result in the formation of 3-acylbutenolides. These reactions appear to proceed through intermediate 2,3-dehydropyrans (strained cyclic allenes), which then isomerize in a previously unobserved fashion. Competitive pro...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Wang, Yuanxian, Hoye, Thomas R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6400065/
https://ncbi.nlm.nih.gov/pubmed/29999326
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b01705
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