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Intramolecular Capture of HDDA-derived Benzynes: i) 6- to 12-Membered Ring Formation, ii) Internally (vis-à-vis Remotely) Tethered Traps, and iii) Role of the Rate of Trapping by the Benzynophile

Reported here are studies that have established novel features of the hexadehydro-Diels-Alder (HDDA) reaction of substrates containing tethered trapping moieties. Products having new structural motifs can be created. i) Medium-sized fused rings can be produced by varying the length of the tether. ii...

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Библиографические подробности
Опубликовано в: :Org Lett
Главные авторы: Wang, Yuanxian, Hoye, Thomas R.
Формат: Artigo
Язык:Inglês
Опубликовано: 2017
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6352971/
https://ncbi.nlm.nih.gov/pubmed/29244510
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b03436
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