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Intramolecular Capture of HDDA-derived Benzynes: i) 6- to 12-Membered Ring Formation, ii) Internally (vis-à-vis Remotely) Tethered Traps, and iii) Role of the Rate of Trapping by the Benzynophile
Reported here are studies that have established novel features of the hexadehydro-Diels-Alder (HDDA) reaction of substrates containing tethered trapping moieties. Products having new structural motifs can be created. i) Medium-sized fused rings can be produced by varying the length of the tether. ii...
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| Publicado no: | Org Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6352971/ https://ncbi.nlm.nih.gov/pubmed/29244510 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b03436 |
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