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Alder-ene reactions driven by high steric strain and bond angle distortion to form benzocyclobutenes
A unique aryne-based Alder-ene reaction to form benzocyclobutene is described. In this process, the thermodynamic barrier to form a four-membered ring is compensated by the relief of the strain energy of an aryne intermediate. On the other hand, the driving force to overcome the high kinetic barrier...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6399677/ https://ncbi.nlm.nih.gov/pubmed/30931094 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04277b |
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