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Synthesis of optically pure γPNA monomers: a comparative study

We report a systematic study examining two synthetic routes, reductive amination and Mitsunobu coupling, for preparation of chiral γ-peptide nucleic acid (γPNA) monomers and oligomers. We found that the reductive amination route is prone to epimerization, even under mild experimental conditions. The...

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發表在:Tetrahedron
Main Authors: Manna, Arunava, Rapireddy, Srinivas, Sureshkumar, Gopalsamy, Ly, Danith H.
格式: Artigo
語言:Inglês
出版: 2015
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6379906/
https://ncbi.nlm.nih.gov/pubmed/30792557
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.03.052
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