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Direct Synthesis of Phosphonates and α-Amino-phosphonates from 1,3-Benzoxazines
A straightforward and novel method for transformation of readily available 1,3-benzoxazines to secondary phosphonates and α-aminophosphonates using boron trifluoride etherate as catalyst is developed. The formation of phosphonates proceeds through ortho-quinone methide (o-QM) generated in situ, foll...
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| Published in: | Molecules |
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| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
MDPI
2019
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6359518/ https://ncbi.nlm.nih.gov/pubmed/30650579 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24020294 |
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