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Oxygen uptake in complexes related to [NiFeS]- and [NiFeSe]-hydrogenase active sites
A biomimetic study for S/Se oxygenation in Ni(μ-EPh)(μ-SN(2))Fe, (E = S or Se; SN(2) = Me-diazacycloheptane-CH(2)CH(2)S); Fe = (η(5)-C(5)H(5))Fe(II)(CO) complexes related to the oxygen-damaged active sites of [NiFeS]/[NiFeSe]-H(2)ases is described. Mono- and di-oxygenates (major and minor species, r...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6354737/ https://ncbi.nlm.nih.gov/pubmed/30809352 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04436h |
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