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Synthetic Active Site Model of the [NiFeSe] Hydrogenase
A dinuclear synthetic model of the [NiFeSe] hydrogenase active site and a structural, spectroscopic and electrochemical analysis of this complex is reported. [NiFe(‘S(2)Se(2)’)(CO)(3)] (H(2)‘S(2)Se(2)’=1,2-bis(2-thiabutyl-3,3-dimethyl-4-selenol)benzene) has been synthesized by reacting the nickel se...
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| Udgivet i: | Chemistry |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
WILEY-VCH Verlag
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4510704/ https://ncbi.nlm.nih.gov/pubmed/25847470 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201500311 |
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