Oxygen uptake in complexes related to [NiFeS]- and [NiFeSe]-hydrogenase active sites

A biomimetic study for S/Se oxygenation in Ni(μ-EPh)(μ-SN(2))Fe, (E = S or Se; SN(2) = Me-diazacycloheptane-CH(2)CH(2)S); Fe = (η(5)-C(5)H(5))Fe(II)(CO) complexes related to the oxygen-damaged active sites of [NiFeS]/[NiFeSe]-H(2)ases is described. Mono- and di-oxygenates (major and minor species, r...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Yang, Xuemei, Elrod, Lindy C., Reibenspies, Joseph H., Hall, Michael B., Darensbourg, Marcetta Y.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Royal Society of Chemistry 2018
Onderwerpen:
Chemistry
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6354737/
https://ncbi.nlm.nih.gov/pubmed/30809352
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04436h
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