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Enantioselective α-functionalizations of ketones via allylic substitution of silyl enol ethers

The enantioselective construction of carbon–heteroatom and carbon–carbon bonds alpha to ketones forms substructures that are ubiquitous in natural products, pharmaceuticals and agrochemicals. Traditional methods to form such bonds have relied on combining ketone enolates with electrophiles. Reaction...

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Detalhes bibliográficos
Publicado no:Nat Chem
Main Authors: He, Zhi-Tao, Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6347495/
https://ncbi.nlm.nih.gov/pubmed/30455430
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41557-018-0165-x
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