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Use of the Dehydrophos Biosynthetic Enzymes to Prepare Antimicrobial Analogs of Alaphosphin

The C-terminal domain of the dehydrophos biosynthetic enzyme DhpH (DhpH-C) catalyzes the condensation of Leu-tRNA(Leu) with (R)-1-aminoethylphosphonate, the aminophosphonate analog of alanine called Ala(P). The product of this reaction, Leu-Ala(P), is a phosphonodipeptide, a class of compounds that...

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Detalhes bibliográficos
Publicado no:Org Biomol Chem
Main Authors: Bougioukou, Despina J., Ting, Chi P., Peck, Spencer C., Mukherjee, Subha, van der Donk, Wilfred A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6344287/
https://ncbi.nlm.nih.gov/pubmed/30608108
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8ob02860e
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