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Biosynthesis of Heptacyclic Duclauxins Requires Extensive Redox Modifications of the Phenalenone Aromatic Polyketide
Duclauxins are dimeric and heptacyclic fungal polyketides significant bioactivities. We characterized the cascade of redox transformations in the biosynthesis of duclauxin pathway from Talaromyces stipitatus. The redox reaction sequence is initiated by a cupin family dioxygenase DuxM that performs a...
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| Vydáno v: | J Am Chem Soc |
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| Hlavní autoři: | , , , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2018
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6309916/ https://ncbi.nlm.nih.gov/pubmed/29741874 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b03705 |
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