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Total Synthesis of Unsymmetrically Oxidized Nuphar Thioalkaloids via Copper-Catalyzed Thiolane Assembly
An asymmetric total synthesis of (+)-6-hydroxythiobinupharidine (1b) and (−)-6-hydroxythionuphlutine (2b), a set of hemiaminal containing dimeric sesquiterpenes isolated from yellow water lilies of the Nuphar genus, is described. The central bis-spirocyclic tetrahydrothiophene ring was forged throug...
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| Vydáno v: | J Am Chem Soc |
|---|---|
| Hlavní autoři: | , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2017
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6309176/ https://ncbi.nlm.nih.gov/pubmed/28911224 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07685 |
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