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Total Synthesis of (+)-Guadinomic Acid via Hydroxyl-Directed Guanidylation
Protecting-group-free total synthesis of (+)-guadinomic acid is reported using δ-valerolactone as a readily available starting material. The protocol utilizes the recent hydroxyl-directed guanidylation of unactivated alkenes as an approach for direct stereoselective incorporation of the guanidine un...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6309422/ https://ncbi.nlm.nih.gov/pubmed/29893133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b01214 |
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