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Concise Synthesis of (+)-[(13)C(4)]-Anatoxin-a by Dynamic Kinetic Resolution of a Cyclic Iminium Ion
An asymmetric total synthesis of [(13)C(4)]-anatoxina ([(13)C(4)]-1) has been developed from commercially available ethyl [(13)C(4)]-acetoacetate ([(13)C(4)]-15). The unique requirements associated with isotope incorporation inspired a new, robust, and highly scalable route, providing access to 0.11...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7409530/ https://ncbi.nlm.nih.gov/pubmed/32304178 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202004464 |
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