Meroterpenoid Synthesis via Sequential Polyketide Aromatization and Cationic Polyene Cyclization: Total Syntheses of (+)-Hongoquercin A and B and Related Meroterpenoids

[Image: see text] (+)-Hongoquercin A and B were synthesized from commercially available trans,trans-farnesol in six and eleven steps, respectively, using dual biomimetic strategies with polyketide aromatization and subsequent polyene functionalization from a common farnesyl-resorcylate intermediate....

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Publicat a:J Org Chem
Autors principals: Ma, Tsz-Kan, Elliott, Daniel C., Reid, Stephanie, White, Andrew J. P., Parsons, Philip J., Barrett, Anthony G. M.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2018
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6303087/
https://ncbi.nlm.nih.gov/pubmed/30346765
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b02095
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