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Enhanced Reactivity of Aluminum Complexes Containing P-Bridged Biphenolate Ligands in Ring-Opening Polymerization Catalysis
Aluminum complexes containing [RP(O)(2-O-3,5-tBu(2)C(6)H(2))(2)](2−) [R = tBu (3a), Ph (3b)] have been synthesized, structurally characterized, and their reactivity studied in comparison with those of their [RP(2-O-3,5-tBu(2)C(6)H(2))(2)](2−) [R = tBu (2a), Ph (2b)] analogs. Treating AlMe(3) with on...
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| Publicado no: | Front Chem |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Frontiers Media S.A.
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6300491/ https://ncbi.nlm.nih.gov/pubmed/30619816 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2018.00607 |
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