Aluminum porphyrins with quaternary ammonium halides as catalysts for copolymerization of cyclohexene oxide and CO(2): metal–ligand cooperative catalysis

Bifunctional Al(III) porphyrins with quaternary ammonium halides, 2-Cl and 2-Br, worked as excellent catalysts for the copolymerization of cyclohexene oxide (CHO) and CO(2) at 120 °C. Turnover frequency (TOF) and turnover number (TON) reached 10 000 h(–1) and 55 000, respectively, and poly(cyclohexe...

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Publicat a:Chem Sci
Autors principals: Deng, Jingyuan, Ratanasak, Manussada, Sako, Yuma, Tokuda, Hideki, Maeda, Chihiro, Hasegawa, Jun-ya, Nozaki, Kyoko, Ema, Tadashi
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2020
Matèries:
Chemistry
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7425082/
https://ncbi.nlm.nih.gov/pubmed/32864082
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01609h
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